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Electrophilic addition to C=C and CC; nucleophilic addition to C=O, CN, conjugated olefins and carbonyls.
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· Electrophilic addition to C=C and C=C; nucleophilic addition to C=O, C=N,conjugated olefins and carbonyls.
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13. Coordination Chemistry : (i) Bonding from the changeover of metallic complexes. Valence bond principle, crystal industry concept and its modifications; programs of theories within the explanation of magnetism and Digital spectra of steel complexes. (ii) Isomerism in coordination compounds; IUPAC nomenclature of coordination compounds; stereochemistry of complexes with four and six coordination figures; chelate result and polynuclear complexes; trans result and its theories; kinetics of substitution reactions in sq.-planar complexes; thermodynamic and kinetic steadiness of complexes.
Micro and macro states; canonical ensemble and canonical partition purpose; electronic, rotational and vibrational partition capabilities and thermodynamic portions; chemical equilibrium in ideal gasoline reactions.
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